Another Example for the Ability of the $rm SbS^{3-}_{3}$ Anion to act as a Bidentate Ligand: Solvothermal Synthesis, Crystal Structure, Calculated and Experimental Raman Spectra of [Cr(tren)SbS3]·H2O
Identifieur interne : 001447 ( Main/Exploration ); précédent : 001446; suivant : 001448Another Example for the Ability of the $rm SbS^{3-}_{3}$ Anion to act as a Bidentate Ligand: Solvothermal Synthesis, Crystal Structure, Calculated and Experimental Raman Spectra of [Cr(tren)SbS3]·H2O
Auteurs : Karina Möller ; Christian N Ther ; Alexander Bannwarth ; Wolfgang Bensch [Allemagne]Source :
- ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2007-11.
English descriptors
- Teeft :
- Acta crystallogr, Allg, Anion, Anorg, Bensch, Bidentate ligand, Bond lengths, Chem, Crystal structure, Hydrogen bonds, Inorg, Kiebach, Ligand, Naturforsch, Raman, Raman spectra, Sbs3, Schur, Solid state, Solid state chem, Solvothermal, Solvothermal conditions, Solvothermal synthesis, Structural parameters, Title compound, Tren, Tren ligand, Verlag gmbh, Water molecules.
Abstract
The new charge neutral complex [Cr(tren)SbS3]·H2O was synthesized under solvothermal conditions applying CrCl3·6H2O, Sb2S3, and S as starting material in an aqueous tren solution (tren = tris(2‐aminoethyl)amine)). The compound crystallizes in the non‐centrosymmetric space group P212121 with a = 8.7779(15), b = 10.7122(17), c = 15.4286(18) Å, V = 1450.8(4) Å3. In the structure the Cr3+ ion is surrounded by four N atoms of the amine molecules and by two S atoms of a trigonal pyramidal [SbS3]3− group, i.e., the latter acts as a bidentate ligand. A three‐dimensional network is formed via hydrogen bonds between the complexes and water molecules. The main resonances in the Raman spectrum can be explained on the basis of calculated data. The most intense band is due to the Sb‐S stretching vibration. The thermal properties were investigated by DTA‐TG measurements. On heating [Cr(tren)SbS3]·H2O decomposes in two distinct steps. The first step corresponds to the removal of the water molecules and the second step to the loss of the tren ligand.
Url:
DOI: 10.1002/zaac.200700378
Affiliations:
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Another Example for the Ability of the $rm SbS^{3-}_{3}$ Anion to act as a Bidentate Ligand: Solvothermal Synthesis, Crystal Structure, Calculated and Experimental Raman Spectra of [Cr(tren)SbS3]·H2O</title><author><name sortKey="Moller, Karina" sort="Moller, Karina" uniqKey="Moller K" first="Karina" last="Möller">Karina Möller</name></author><author><name sortKey="N Ther, Christian" sort="N Ther, Christian" uniqKey="N Ther C" first="Christian" last="N Ther">Christian N Ther</name></author><author><name sortKey="Bannwarth, Alexander" sort="Bannwarth, Alexander" uniqKey="Bannwarth A" first="Alexander" last="Bannwarth">Alexander Bannwarth</name></author><author><name sortKey="Bensch, Wolfgang" sort="Bensch, Wolfgang" uniqKey="Bensch W" first="Wolfgang" last="Bensch">Wolfgang Bensch</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:6E8BE626BA6B4AC2B345CBF1F9911849ABA21B30</idno><date when="2007" year="2007">2007</date><idno type="doi">10.1002/zaac.200700378</idno><idno type="url">https://api.istex.fr/ark:/67375/WNG-BZ8NVWB9-S/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">000D86</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000D86</idno><idno type="wicri:Area/Istex/Curation">000D86</idno><idno type="wicri:Area/Istex/Checkpoint">000430</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000430</idno><idno type="wicri:doubleKey">0044-2313:2007:Moller K:another:example:for</idno><idno type="wicri:Area/Main/Merge">001465</idno><idno type="wicri:Area/Main/Curation">001447</idno><idno type="wicri:Area/Main/Exploration">001447</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main">Another Example for the Ability of the $\rm SbS^{3-}_{3}$ Anion to act as a Bidentate Ligand: Solvothermal Synthesis, Crystal Structure, Calculated and Experimental Raman Spectra of [Cr(tren)SbS3]·H2O</title><author><name sortKey="Moller, Karina" sort="Moller, Karina" uniqKey="Moller K" first="Karina" last="Möller">Karina Möller</name><affiliation><wicri:noCountry code="subField">Chemie</wicri:noCountry></affiliation></author><author><name sortKey="N Ther, Christian" sort="N Ther, Christian" uniqKey="N Ther C" first="Christian" last="N Ther">Christian N Ther</name><affiliation><wicri:noCountry code="subField">Chemie</wicri:noCountry></affiliation></author><author><name sortKey="Bannwarth, Alexander" sort="Bannwarth, Alexander" uniqKey="Bannwarth A" first="Alexander" last="Bannwarth">Alexander Bannwarth</name><affiliation><wicri:noCountry code="subField">Chemie</wicri:noCountry></affiliation></author><author><name sortKey="Bensch, Wolfgang" sort="Bensch, Wolfgang" uniqKey="Bensch W" first="Wolfgang" last="Bensch">Wolfgang Bensch</name><affiliation></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Allemagne</country></affiliation><affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="ISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><imprint><biblScope unit="vol">633</biblScope><biblScope unit="issue">15</biblScope><biblScope unit="page" from="2635">2635</biblScope><biblScope unit="page" to="2640">2640</biblScope><biblScope unit="page-count">6</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2007-11">2007-11</date></imprint><idno type="ISSN">0044-2313</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-2313</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Acta crystallogr</term><term>Allg</term><term>Anion</term><term>Anorg</term><term>Bensch</term><term>Bidentate ligand</term><term>Bond lengths</term><term>Chem</term><term>Crystal structure</term><term>Hydrogen bonds</term><term>Inorg</term><term>Kiebach</term><term>Ligand</term><term>Naturforsch</term><term>Raman</term><term>Raman spectra</term><term>Sbs3</term><term>Schur</term><term>Solid state</term><term>Solid state chem</term><term>Solvothermal</term><term>Solvothermal conditions</term><term>Solvothermal synthesis</term><term>Structural parameters</term><term>Title compound</term><term>Tren</term><term>Tren ligand</term><term>Verlag gmbh</term><term>Water molecules</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The new charge neutral complex [Cr(tren)SbS3]·H2O was synthesized under solvothermal conditions applying CrCl3·6H2O, Sb2S3, and S as starting material in an aqueous tren solution (tren = tris(2‐aminoethyl)amine)). The compound crystallizes in the non‐centrosymmetric space group P212121 with a = 8.7779(15), b = 10.7122(17), c = 15.4286(18) Å, V = 1450.8(4) Å3. In the structure the Cr3+ ion is surrounded by four N atoms of the amine molecules and by two S atoms of a trigonal pyramidal [SbS3]3− group, i.e., the latter acts as a bidentate ligand. A three‐dimensional network is formed via hydrogen bonds between the complexes and water molecules. The main resonances in the Raman spectrum can be explained on the basis of calculated data. The most intense band is due to the Sb‐S stretching vibration. The thermal properties were investigated by DTA‐TG measurements. On heating [Cr(tren)SbS3]·H2O decomposes in two distinct steps. The first step corresponds to the removal of the water molecules and the second step to the loss of the tren ligand.</div></front></TEI><affiliations><list><country><li>Allemagne</li></country></list><tree><noCountry><name sortKey="Bannwarth, Alexander" sort="Bannwarth, Alexander" uniqKey="Bannwarth A" first="Alexander" last="Bannwarth">Alexander Bannwarth</name><name sortKey="Moller, Karina" sort="Moller, Karina" uniqKey="Moller K" first="Karina" last="Möller">Karina Möller</name><name sortKey="N Ther, Christian" sort="N Ther, Christian" uniqKey="N Ther C" first="Christian" last="N Ther">Christian N Ther</name></noCountry><country name="Allemagne"><noRegion><name sortKey="Bensch, Wolfgang" sort="Bensch, Wolfgang" uniqKey="Bensch W" first="Wolfgang" last="Bensch">Wolfgang Bensch</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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